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Plastics & Elastomers
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Plastics & Elastomers

Strength at Break (Tensile)


Tensile strength of plastics
  1. What is the definition of tensile strength?
  2. What are the three types of tensile strength?
  3. What is tensile strength at break?
  4. What are the units of tensile strength?
  5. Which materials show high tensile strength?
  6. How stress-strain curve measures the tensile strength?
  7. What is the significance of tensile properties?
  8. What are the factors affecting the tensile strength?
  9. What are the test methods to measure tensile properties?
  10. What are the tensile strength at break values of several plastics?


What is the definition of tensile strength?


Tensile strength is the ability of plastic material to withstand a maximum amount of tensile stress without failure. The stress occurs while the material is being pulled or stretched. It is the point when a material goes from elastic to plastic deformation.

While removing the stress, the plastic material undergoes:

  • Elastic deformation: The material returns to its original dimensions. Deformation is reversible and non-permanent. Valid for small strains.
  • Plastic deformation: The material does not return to its original dimensions. This process is permanent and irreversible.


What are the three types of tensile strength?


There are three types of tensile strength:

  • Yield strength (A) - The stress a material can withstand without permanent deformation. Know more »
  • Ultimate strength (B) - The maximum stress a material can withstand
  • Breaking strength (C) - The stress coordinate on the stress-strain curve at the point of rupture

Stress-Strain Graph
Stress-strain curve showing tensile strength at points Yield (A), Ultimate Strength (B) and Break (C)

In other words, materials first deform elastically - when you release the stress they return to their original shape. Then with more force they deform plastically, this is yield - when you release the stress they have permanently been stretched into a new shape. Finally, they break; this is ultimately tensile stress or breaking point.

Tensile strength is often referred to as ultimate tensile strength


What is tensile strength at break?


Tensile strength (TS) at break measures the maximum stress a plastic specimen can withstand while being stretched before breaking. Some materials can break sharply (brittle failure). While others will deform or elongate before breaking. It is measured as the tensile or compressive load required to fracture something. It is also known as break strength.

Hence, it is one of the important mechanical properties for:

  • Material evaluation
  • Quality control
  • Structure design
  • Modeling, and
  • Failure analysis


What are the units of tensile strength?


Tensile strength is measured in units of force per cross-sectional area. In the International System, the units of Tensile Strength are:

  • Pascal (Pa)
  • Megapascals (MPa)
  • Gigapascals (GPa)

In the US, the commonly used units for convenience when measuring tensile strengths are:

  • Pounds-force per square inch (lbf/in2 or psi)
  • Kilo-pounds per square inch (kpsi)


Tensile Strength of Plastics

Which materials show high tensile strength?


  1. Thermoplastics with High Tensile Strength – View Product List

  2. Thermoplastic Elastomers with High Tensile Strength – View Product List

  3. Thermosets with High Tensile Strength – View Product List

  4. Rubbers with High Tensile Strength – View Product List


How stress-strain curve measures the tensile strength?


When a stretching force or tensile force is applied to an object, it extends. Its behavior can be obtained using a stress-strain curve in the elastic deformation region. This is known as Hooke’s Law. The extension that a force produces depends on the plastic material and dimensions of the object.

Definition of stress


Stress is defined as the force per unit area of plastic. The units of stress are N/m2 or Pa.

σ = F/A

where,
  • σ is the stress,
  • F is the force, and
  • A is the cross-sectional area of the sample.

Definition of strain


Strain is defined as extension per unit length. And, since it is a ratio of lengths, the strain has no units.

ε = ΔL/L0; ΔL = L-L0

where,
  • ε is the strain,
  • L0 is the original length of a bar being stretched,
  • L is the length after it has been stretched, and
  • ΔL is the extension of the bar, the difference between these two lengths.

Stress-Strain Plots of Plastics
Stress-Strain Plots for a Typical Elastomer, Flexible Plastics, Rigid Plastic, and Fiber
(Source: Principles of Polymerization, Fourth Edition, George Odian)


What is the significance of tensile properties?


  • Tensile properties provide useful data for plastics engineering design purposes.
  • They are frequently included in material specifications to ensure quality.
  • They are often measured during the development of new materials and processes. This is done to compare different materials and processes.
  • They predict the behavior of a material under various forms of loading other than uniaxial tension.


What are the factors affecting the tensile strength of plastics?


The strength of polymers is further governed by:

Molecular weight


The strength of the polymer rises with the increase in molecular weight. It reaches the saturation level at some value of the molecular weight.

  • At lower molecular weight: The polymer chains are loosely bonded by weak van der Waals forces. The chains can move easily and are responsible for low strength. Although crystallinity is present.
  • At higher molecular weight: The polymer chains become large. Hence, crosslinking takes place giving strength to the polymer.


Crosslinking between polymer chains


The crosslinking restricts the motion of the chains. This increases the strength of the polymer.


Crystallinity


The crystalline phase of the polymer increases the tensile strength. Hence the intermolecular bonding is more significant. Therefore, the polymer deformation can result in higher strength leading to oriented chains.


Other factors that impact the tensile strength values of plastics


  • Velocity of testing,
  • Orientation level of fibers,
  • Temperature,
  • Filler content, etc.


What are the test methods to measure tensile properties of plastics?


In general, “tensile test methods” measure the modulus of elasticity of materials. The common methods used are:

  • ASTM D638 - Standard Test Method for Tensile Properties of Plastics
  • ISO 527-1:2012 - Determination of tensile properties. General principles

These methods determine the tensile properties of plastics and plastic composites. This is done under defined conditions that can range from:

  • pretreatment,
  • temperature,
  • humidity, and
  • machine speed

The test specimens are in the form of a standard dumbbell shaped.

For ASTM D638, the test speed is determined by the material specification. For ISO 527, the test speed is typically 5 or 50 mm/min for measuring strength and elongation, and 1 mm/min for measuring modulus.


Watch this Interesting Video on Micro Tensile Strength Test of Plastics per ASTM D638
(Source: ADMET)

Apart from Tensile strength at break, the tensile test results can also calculate:


What are the tensile strength at break values of several plastics?


Click to find polymer you are looking for:
A-C     |      E-M     |      PA-PC     |      PE-PL     |      PM-PP     |      PS-X

Polymer Name Min Value (MPa) Max Value (MPa)
ABS - Acrylonitrile Butadiene Styrene 
29.8 43.0
ABS Flame Retardant
30.0 50.0
ABS High Heat 30.0 60.0
ABS High Impact 30.0 45.0
ABS/PC Blend - Acrylonitrile Butadiene Styrene/Polycarbonate Blend
40.0 50.0
ABS/PC Blend 20% Glass Fiber 75.0 80.0
ABS/PC Flame Retardant
40.0 55.0
Amorphous TPI Blend, Ultra-high heat, Chemical Resistant (High Flow) 105.0 105.0
Amorphous TPI Blend, Ultra-high heat, Chemical Resistant (Standard Flow) 160.0 160.0
Amorphous TPI, High Heat, High Flow, Lead-Free Solderable, 30% GF 147.0 147.0
Amorphous TPI, High Heat, High Flow, Transparent, Lead-Free Solderable (High Flow) 74.0 74.0
Amorphous TPI, High Heat, High Flow, Transparent, Lead-Free Solderable (Standard Flow) 70.0 70.0
Amorphous TPI, Highest Heat, Chemical Resistant, 260C UL RTI 119.0 119.0
Amorphous TPI, Moderate Heat, Transparent 78.0 78.0
Amorphous TPI, Moderate Heat, Transparent (Food Contact Approved) 78.0 78.0
Amorphous TPI, Moderate Heat, Transparent (Mold Release grade) 78.0 78.0
Amorphous TPI, Moderate Heat, Transparent (Powder form) 78.0 78.0
ASA - Acrylonitrile Styrene Acrylate
47.0 56.0
ASA/PC Blend - Acrylonitrile Styrene Acrylate/Polycarbonate Blend
45.0 50.0
ASA/PC Flame Retardant 48.0 48.0
ASA/PVC Blend - Acrylonitrile Styrene Acrylate/Polyvinyl Chloride Blend 45.0 50.0
CA - Cellulose Acetate
24.0 52.0
CAB - Cellulose Acetate Butyrate
18.0 48.0
CP - Cellulose Proprionate 14.0 50.0
COC - Cyclic Olefin Copolymer
46.0 63.0
CPVC - Chlorinated Polyvinyl Chloride 
45.0 60.0
ETFE - Ethylene Tetrafluoroethylene 
45.0 45.0
ECTFE 45.0 54.0
EVA - Ethylene Vinyl Acetate
7.0 30.0
EVOH - Ethylene Vinyl Alcohol
30.0 205.0
FEP - Fluorinated Ethylene Propylene
19.0 21.0
HDPE - High Density Polyethylene
30.0 40.0
HIPS - High Impact Polystyrene
20.0 45.0
HIPS Flame Retardant V0 15.0 30.0
Ionomer (Ethylene-Methyl Acrylate Copolymer)
11.0 37.0
LCP - Liquid Crystal Polymer
175.0 175.0
LCP Carbon Fiber-reinforced 190.0 240.0
LCP Glass Fiber-reinforced 160.0 220.0
LCP Mineral-filled 110.0 180.0
LDPE - Low Density Polyethylene
10.0 20.0
LLDPE - Linear Low Density Polyethylene
25.0 45.0
PA 11 - (Polyamide 11) 30% Glass fiber reinforced
80.0 136.0
PA 11, Conductive 37.0 37.0
PA 11, Flexible 43.0 59.0
PA 11, Rigid 37.0 58.0
PA 12 (Polyamide 12), Conductive 39.0 -
PA 12, Fiber-reinforced 72.0 145.0
PA 12, Flexible 50.0 56.0
PA 12, Glass Filled 37.0 50.0
PA 12, Rigid 56.0 69.0
PA 46 - Polyamide 46
65.0 85.0
PA 46, 30% Glass Fiber 128.0 132.0
PA 6 - Polyamide 6
50.0 95.0
PA 6-10 - Polyamide 6-10
50.0 65.0
PA 66 - Polyamide 6-6
50.0 95.0
PA 66, 30% Glass Fiber 100.0 125.0
PA 66, 30% Mineral filled 45.0 200.0
PA 66, Impact Modified, 15-30% Glass Fiber 90.0 120.0
PA 66, Impact Modified
40.0 50.0
Polyamide semi-aromatic 60.0 60.0
PAI - Polyamide-Imide
190.0 195.0
PAI, 30% Glass Fiber 210.0 210.0
PAI, Low Friction 125.0 165.0
PAN - Polyacrylonitrile 50.0 65.0
PAR - Polyarylate 
25.0 65.0
PARA (Polyarylamide), 30-60% glass fiber
190.0 280.0
PBT - Polybutylene Terephthalate
40.0 50.0
PBT, 30% Glass Fiber 135.0 140.0
PC (Polycarbonate) 20-40% Glass Fiber 90.0 160.0
PC (Polycarbonate) 20-40% Glass Fiber Flame Retardant 90.0 140.0
PC - Polycarbonate, high heat
55.0 77.0
PC/PBT Blend - Polycarbonate/Polybutylene Terephthalate Blend Glass Filled 62.0 110.0
PCTFE - Polymonochlorotrifluoroethylene
32.0 40.0
PE - Polyethylene 30% Glass Fiber
52.0 63.0
PEEK - Polyetheretherketone
90.0 150.0
PEEK 30% Carbon Fiber-reinforced 200.0 220.0
PEEK 30% Glass Fiber-reinforced 150.0 180.0
PEI - Polyetherimide
90.0 100.0
PEI, 30% Glass Fiber-reinforced 150.0 160.0
PEI, Mineral Filled
90.0 100.0
PEKK (Polyetherketoneketone), Low Crystallinity Grade
89.5 89.5
PESU - Polyethersulfone
70.0 90.0
PESU 10-30% glass fiber 75.0 140.0
PET - Polyethylene Terephthalate
45.0 70.0
PET, 30% Glass Fiber-reinforced 140.0 160.0
PET, 30/35% Glass Fiber-reinforced, Impact Modified 100.0 110.0
PETG - Polyethylene Terephthalate Glycol
40.0 40.0
PE-UHMW - Polyethylene -Ultra High Molecular Weight 39.0 49.0
PFA - Perfluoroalkoxy
27.0 30.0
PGA - Polyglycolides 68.9 68.9
PHB - Polyhydroxybutyrate
25.0 27.0
PHB-V(5% valerate) 35.0 37.0
PI - Polyimide
72.0 120.0
PLA - Polylactide
52.0 54.0
PLA - Polylactide High heat films 102.2 104.2
PMMA - Polymethylmethacrylate/Acrylic
38.0 70.0
PMMA (Acrylic) High Heat 65.0 79.0
PMMA (Acrylic) Impact Modified
35.0 65.0
PMP - Polymethylpentene
16.0 18.0
PMP 30% Glass Fiber-reinforced 60.0 68.0
PMP Mineral Filled 17.0 18.0
Polyamide 66 (Nylon 66)/Carbon Fiber, Long, 30% Filler by Weight 290.0 290.0
Polyamide 66 (Nylon 66)/Carbon Fiber, Long, 40% Filler by Weight 305.0 305.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 40% Filler by Weight 230.0 230.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 40% Filler by Weight 210.0 210.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 50% Filler by Weight 270.0 270.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 50% Filler by Weight 230.0 230.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 60% Filler by Weight 270.0 270.0
Polyamide 66 (Nylon 66)/Glass Fiber, Long, 60% Filler by Weight 250.0 250.0
Polypropylene Homopolymer (PP Homopolymer)/Glass Fiber, Long, 30% Filler by Weight 120.0 120.0
Polypropylene Homopolymer (PP Homopolymer)/Glass Fiber, Long, 40% Filler by Weight 130.0 130.0
Polypropylene Homopolymer (PP Homopolymer)/Glass Fiber, Long, 40% Filler by Weight 120.0 120.0
Polypropylene Homopolymer (PP Homopolymer)/Glass Fiber, Long, 50% Filler by Weight 130.0 130.0
Polypropylene Homopolymer (PP Homopolymer)/Glass Fiber, Long, 50% Filler by Weight 130.0 130.0
POM - Polyoxymethylene (Acetal)
60.0 70.0
POM (Acetal) Impact Modified
45.0 60.0
POM (Acetal) Low Friction 50.0 70.0
POM (Acetal) Mineral Filled
50.0 75.0
PP - Polypropylene 10-20% Glass Fiber
35.0 56.0
PP, 10-40% Mineral Filled 18.0 24.0
PP, 10-40% Talc Filled 21.0 28.0
PP, 30-40% Glass Fiber-reinforced 42.0 70.0
PP (Polypropylene) Copolymer
30.0 35.0
PP (Polypropylene) Homopolymer
20.0 40.0
PP, Impact Modified
23.0 35.0
PPA - Polyphthalamide
85.0 85.0
PPA, 30% Mineral-filled 79.0 81.0
PPA, 33% Glass Fiber-reinforced 192.0 194.0
PPA, 33% Glass Fiber-reinforced – High Flow 162.0 163.0
PPA, 45% Glass Fiber-reinforced 227.0 229.0
PPE - Polyphenylene Ether
45.0 60.0
PPE, 30% Glass Fiber-reinforced 100.0 130.0
PPE, Flame Retardant 45.0 55.0
PPE, Impact Modified 45.0 55.0
PPE, Mineral Filled 65.0 75.0
PPS - Polyphenylene Sulfide
50.0 80.0
PPS, 20-30% Glass Fiber-reinforced 130.0 150.0
PPS, 40% Glass Fiber-reinforced 120.0 150.0
PPS, Conductive 60.0 140.0
PPS, Glass fiber & Mineral-filled 60.0 150.0
PPSU - Polyphenylene Sulfone
75.8 76.0
PS (Polystyrene) 30% glass fiber 70.0 70.0
PS (Polystyrene) Crystal 35.0 60.0
PS, High Heat 40.0 60.0
PSU - Polysulfone
70.0 80.0
PSU, 30% Glass fiber-reinforced 100.0 125.0
PSU Mineral Filled 65.0 70.0
PTFE - Polytetrafluoroethylene
0.0 10.0
PTFE, 25% Glass Fiber-reinforced 15.0 20.0
PVC (Polyvinyl Chloride), 20% Glass Fiber-reinforced             
60.0 90.0
PVC, Plasticized
7.0 25.0
PVC, Plasticized Filled 10.0 25.0
PVC Rigid
35.0 60.0
PVDC - Polyvinylidene Chloride
20.0 35.0
PVDF - Polyvinylidene Fluoride
40.0 50.0
SAN - Styrene Acrylonitrile
65.0 85.0
SAN, 20% Glass Fiber-reinforced 100.0 120.0
SMA - Styrene Maleic Anhydride
35.0 55.0
SMA, 20% Glass Fiber-reinforced 56.0 75.0
SMA, Flame Retardant V0 20.0 25.0
SMMA - Styrene Methyl Methacrylate
30.0 60.7
SRP - Self-reinforced Polyphenylene 159.0 207.0
TPS/PE - Thermoplastic Starch/ Polyethylene Blend (30 micron films tested) 20.0 20.0
XLPE - Crosslinked Polyethylene
11.0 32.0

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