Industry News

New Way to Develop Thermoplastic Rubber Material with High Impact Strength

Published on 2021-12-22. Edited By : SpecialChem

TAGS:  Automotive   

new-elastomeric-material Nagoya University and the Zeon Corporation have developed a new thermoplastic rubber material, based on a type of ionically-functionalized block polymer called "i-SIS", with a high impact resistance - higher than glass-fiber-reinforced plastic.

Industry-Friendly Synthesis of Chemically Modified SIS

To improve the mechanical properties of styrenic block polymers, Nagoya University and the Zeon Corporation report industry-friendly synthesis of chemically modified SIS such as hydrogen-bonded SIS (h-SIS) and "ionically functionalized SIS" (i-SIS) - which is SIS with positive ions such as sodium bonded in it. The "cation" has one (monovalent) electron removed from the outer shell. Preliminary measurements showed that i-SIS has an extremely high tensile toughness of 480 MJ/m3, which is the highest value of any known thermoplastic rubber material as far as we know.

Although a preliminary tensile test is useful for investigating the common mechanical properties of materials, it does not reveal all the mechanical features of the materials, particularly impact resistance that is crucially important in practical applications. Moreover, measuring the impact resistance is also important for understanding the mechanism by which desirable mechanical properties arise in the material, and therefore how they can be achieved.

Evaluate the Impact Resistance of the New Materials

This study by Nagoya University and the Zeon Corporation is the first to evaluate the impact resistance of the new elastomeric materials based on i-SIS and compare them to the impact resistance of a typical high-strength material based on glass-fiber-reinforced plastic (GFRP), which has a tensile strength of 330 MPa.

Drop weight impact tests demonstrated that i-SIS with monovalent or divalent cations is 3 or 4 times more impact resistant than chemically unmodified SIS; moreover, i-SIS with divalent cations is found to be 1.2 times more impact resistant than typical high-strength GFRP. In total, i-SIS, especially with divalent ions, was found to be highly impact resistant, even though inorganic fillers - a typical additive for hardening polymers - are not incorporated into the polymer and the molecular structure of the polymer is not chemically cross-linked.

Automobile and other vehicle manufacturers are continually searching for lighter materials that are also resistant to damage. Since i-SIS can be synthesized on an industrial scale, it has a great potential to become a next-generation elastomeric material for use not only in interior and exterior automobile parts, but also for automobile bodies, and even the outer panels of automobiles, trains, and other vehicles that require structural materials with high impact resistance as well as ease of manufacture. These research achievements will also contribute to the development of lightweight vehicles and the establishment of a carbon-free society.

Source: Nagoya University


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